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    Therefore, the appearance of new modes in the spectra can be a useful indicator of symmetry breakdown. There are many types of coupled transition such as are observed in vibration-rotation spectra.

    The excited-state wave function is the product of two wave functions such as vibrational and rotational.

    The general principle is that the symmetry of the excited state is obtained as the direct product of the symmetries of the component wave functions.

    The infrared spectrum of hydrogen chloride gas shows rotational fine structure superimposed on the vibrational spectrum.

    This is typical of the infrared spectra of heteronuclear diatomic molecules. It shows the so-called P and R branches.

    The Q branch, located at the vibration frequency, is absent. Symmetric top molecules display the Q branch.

    This follows from the application of selection rules. Resonance Raman spectroscopy involves a kind of vibronic coupling. It results in much-increased intensity of fundamental and overtone transitions as the vibrations "steal" intensity from an allowed electronic transition.

    In transitions where the change in angular momentum between the initial and final states makes several multipole radiations possible, usually the lowest-order multipoles are overwhelmingly more likely, and dominate the transition.

    Thus, there is no E0 electric monopoles or M0 magnetic monopoles , which do not seem to exist radiation. Thus, parity does not change for E-even or M-odd multipoles, while it changes for E-odd or M-even multipoles.

    These considerations generate different sets of transitions rules depending on the multipole order and type. Bitte beachte unsere Hinweise zum Jugendschutz und unsere Chatiquette.

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